Document Type : Review Article


1 Department of Chemistry, Sirjan Branch, Islamic Azad University, Sirjan, Iran

2 Department of Management, Sirjan Branch, Islamic Azad University, Sirjan, Iran


The objectives of this experiment were to investigate the application of new ligands including different atoms & evaluation their nucleophile effects against various metals. Chemistry researchers are really interested in this field. From among various ligands, there are some ligands with different coordinating ligands as well. There are great number of intermediate complexes and major elements of organic compositions with various atoms. There is a regular adding of new compositions. Complexes are the most important chemical combinations with various catalysts and biological, medicine and other applications. Those complexes with ligands including different atoms givers are really important and their synthesis could solve most of chemical problems. Supplying of new ligands is an important and key part of coordination chemistry which may cause some varieties and different properties in complexes with equal central nucleus. As a result, this research has evaluated new ligands including different coordination atoms (such as Oxygen, Nitrogen and …) along with their behavior against various metals like Copper, Nickel, Iron and...


1) Mitra Ghassemzadeh, Masoomeh Tabatabaee, Samaneh Soleimani and Bernard Neumuller. Synthesis, Characterization and Crystal Stractures of new 1,2,4-Triazole based Schiff-bases and their Copper(I) Complexes(Z.Anorg.Allg.Chem.631,2005).
2) Mitra Ghassemzadeh, Masoomeh Tabatabaee, Zohreh Mirrokni and Bernard Neumuller. Synthesis,Characterization and Crystal stricture of Dimeric {[(AMTTO)2Ag]NO3}2,(Z.Anorg. Allg Chem.631,2005).
3) Mitra Ghassemzadeh , Masoomeh Tabatabaee , Mostafa M. Pooramini, Majid M. Heravi and Bernard Neumuller. Synthesis and Characterization of the first Copper(II) complex of 6-Azathymine crystal stricture of [CuCl2(H2O)2(AT)]2.2H2O;(AT=Azathymine) (Z.Anorg. Chem.630,2009 .
4) Masoomeh Tabatabaee , Mitra Ghasemzadeh ,Behnaz Zarabi , Majid M. Heravi and Mohammad Anari – Abbasinejad , Solvent – free microwave synthesis of
5) (Aryl – and Hetroaryl – methylene )- Amino – derivatives… thioxo – 2H-1,2,4-triazine. (Z.Anorg. Chem.630,2013)
6) Masoomeh Tabatabaee, Mitra Ghasemzadeh, Behnaz Zarabi and Bernard Neumuller. Synthesis and Crystal structural of Schiff- Based on AMTTO (AMTTO =4 amino ,6-methyl, 3- thio,3,4-dihydro.1,2,4- triazin-5(2H)-one, (Z.Anorg. Chem.632,2004)
7) S. Hajmohammadi, M. Tabatabaee, S. HajmohammadiI, N. B. Ghafoori, M. Parvez, Z. Kristallogr. Crystal structure of N,N'-bis(2-hydroxy-4-methoxysalicylidene)-ethylenediaminatonickel(II), Ni(C18H18N2O4)NCS 226 (2011) 131-132.
8) H.Schiff,Ann.Chem.1864,131,118.
9) S.Dayagi, Y.Degani,”The Chemistry of Of Carbon – Nitrogen Double Bound.,” ed.S.Patai,Willey – interscience, New York,1970,P.61.
10) R.W.Layer,Chem,Rev.,1963,63,489.
11) J.H.Billman,K.M.Taj,J.Org.Chem.1957,23,535.
12) M.E.Talor,T.J.Fletcher,J.Org.Chem.1961,26,946.
13) G.Reddelien,Chem,Ber.,1910,43,2470.
14) D.Y.Curting,J.W.Hausser,J.Amer.Chem,Soc.,1961,83,3414.
15) G.Reddelien,Chem.Ber.,1910,43,2470.
16) J.Kolsa,Arch.Chem.,1954,62,287.
17) R.L.Reeves,Chemistry of the Carbonyl Group .Ed.S.P. Patai., Interscience .,1966,P.567.
18) T.Tsumaki,Bull.Japan Chem.Soc.,1938,13,252.
19) H.Y.Han,Y.L.Song,H.W.Hou,Y.T.Fan,Y.Zhu,J.Chem.Soc.,Dalton Trans.2006,1972 .20) E.Braun,C.D.Steffek,J.Kim,P.G.Rasmussen,O.M.Yaghi,Chem.Commun.,4,2002,401.
21) N.L.Rosi,M.Eddaoudi,J.Kim,M.O’Keeffe,O.M.Yaghi,Cryst.Eng.Commun.,4, 2002,401.
23) B.Chen,M.Eddaoudi,S.T.Hyde,M.O’Keeffe,O.M.Yaghi,Science,291,2001, 1021.
26) P.M.Forster,A.K.Cheetham,Micropor.Mesopor.Mater.,73,2004,57.
27) W.K.Dong,Y.X.Sun,C.Y.Zhao,X.Y.Dong,L.Xu,Polyhedron,29,2010,2087.
28) M.Tabatabaee,M.Ghasemzadeh,B.Zarabi,Heravi,M M.Anary-Abbasinejad ,B.
29) Neumuller ,Phosphorus,Sulfur Silicon,And the Related Elements,182,2007.